Pranyoto, Nugroho, Susanti, Yuni Dewi, Ondang, Immanuel Joseph, Angkawijaya, Artik Elisa, Soetarejo, Felycia Edi, Santoso, Shella Permatasari, Yuliana, Maria, Ismadji, Suryadi and Hartono, Sandy Budi (2022) Facile Synthesis of Silane-Modified Mixed Metal Oxide as Catalyst in Transesterification Processes. Facile Synthesis of Silane-Modified Mixed Metal Oxide as Catalyst in Transesterification Processes, 12 (13). p. 245. ISSN 20794991, Jurnal Internasional Bereputasi SJR(2020): 0.92, Q1, H-Index: 58
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Abstract
The fast depletion of fossil fuels has attracted researchers worldwide to explore alternative biofuels, such as biodiesel. In general, the production of biodiesel is carried out via transesterificationprocesses of vegetable oil with the presence of a suitable catalyst. A mixed metal oxide has shown to be a very attractive heterogeneous catalyst with a high performance. Most of the mixed metaloxide is made by using the general wetness impregnation method. A simple route to synthesize silane-modified mixed metal oxide (CaO-CuO/C6) catalysts has been successfully developed. A fluorocarbon surfactant and triblock copolymers (EO)106(PO)70(EO)106 were used to prevent the crystal agglomeration of carbonate salts (CaCO3-CuCO3) as the precursor to form CaO-CuO with a definite size and morphology. The materials show high potency as a catalyst in the transesterification process to produce biodiesel. The calcined co-precipitation product has a high crystallinity form, as confirmed by the XRD analysis. The synthesized catalyst was characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). The mechanism of surface modification and the effects of the catalytic activity were also discussed. The biodiesel purity of the final product was analyzed by gas chromatography. The optimum biodiesel yield was 90.17% using the modified mixed metal oxide CaO-CuO/C6.
Item Type: | Article |
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Additional Information: | Jurnal Internasional Bereputasi SJR(2020): 0.92, Q1, H-Index: 58 |
Uncontrolled Keywords: | hydrophobic surface modification; mixed metal oxide; biodiesel; transesterification; silanization |
Subjects: | Engineering > Chemical Engineering |
Divisions: | Journal Publication |
Depositing User: | F.X. Hadi |
Date Deposited: | 14 Jul 2022 06:30 |
Last Modified: | 03 Aug 2022 02:17 |
URI: | http://repository.ukwms.ac.id/id/eprint/31537 |
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